Tuning the Photophysical Properties of Photostable Benzo[b]phosphole POxide-Based Fluorophores

Papers published
R. Adler, C. Wang, A. Fukazawa,* S. Yamaguchi,* Inorg. Chem., 2017, ASAP. DOI: 10.1021/acs.inorgchem.7b00658
  • Constrained 2-phenylbenzo[b]phosphole P-oxides bearing diphenylamino groups at the terminal positions as well as carbon- and silicon-bridging moieties were synthesized. The study on the impact of the bridging moieties on their photophysical properties revealed that even the silicon-brdiged compounds show outstanding photostability under irradiation with a xenon lamp, as far as the bridging moieties have sufficient steric bulkiness.

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