A Planarized B-phenyldibenzoborepin: Impact of the Structural Constraint on Its Electronic Properties and Lewis Acidity

Papers published
N. Ando, T. Kushida, and S. Yamaguchi, Chem. Commun., 2018, 54, 5213-5216. DOI: 10.1039/C8CC02837K
  • A B-phenyldibenzo[b,f]borepin planarized with two methylene bridges was synthesized. The structural constraint on the B-phenylgroup resulted in a bathochromic shift of the absorption and fluorescence properties as well as the enhanced Lewis acidity. A donor-π-acceptor type derivative based on this scaffold exhibited intense fluorescence irrespective of the solvent polarity.

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