Planarized B-phenylborataanthracene anions: structural and electronic impacts of coplanar constraint

Papers published
Tomokatsu Kushida, Zhiguo Zhou, Atsushi Wakamiya and Shigehiro Yamaguchi Chem. Commun., 2012, Advance Article DOI: 10.1039/C2CC35874C
  • Potassium and lithium salts of anionic B-phenylborataanthracenes, whose phenyl groups were fixed in a coplanar fashion, were synthesized. These compounds exhibited solvent-separated ion pair structures both in the crystalline state and in solution. Planarization of the phenyl moiety had a remarkable impact on the photophysical properties, such as the red-shifted absorption and intense fluorescence.

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