Constraint-induced structural deformation of planarized triphenylboranes in the excited state

Papers published
Tomokatsu Kushida, Cristopher Camacho, Ayumi Shuto, Stephan Irle, Masayasu Muramatsu, Tetsuro Katayama, Syoji Ito, Yutaka Nagasawa, Hiroshi Miyasaka, Eri Sakuda, Noboru Kitamura, Zhiguo Zhou, Atsushi Wakamiya, and Shigehiro Yamaguchi Chemical Science, 2013. DOI: 10.1039/c3sc52751d
  • Triphenylboranes planarized with three methylene bridges undergo structural deformation from a planar structure to a bowl-shaped structure in the lowest-energy excited singlet state, giving rise to a characteristic dual fluorescence.

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